Studies on the synthesis and properties of poly(amide-azomethine)

Homopolymer and copolymer of poly(amide-azomethine) were synthesized from the corresponding diamines and dialdehydes. The polymerization was proceeded in the mixed solvent of o-chlorophenol and m-cresol (1: I by volume) at 0 °C for I S h. The inherent viscosities of the new aromatic poly(amide-azomethine)s are in the range of 0.51 to 2.31 dl/g. These polymers were soluble in sulfuric and formic acid. The TGA results show that no weight loss up to 400 °C under nitrogen atmosphere, which suggests the relatively good thermal stabilities.     

Air sampling of volatile sex pheromone components in a closed jar

A cotton wool plug, used as the source for pheromone release, was placed in closed 1-quart Mason jars, either at the mouth or at the rear of the jar. Air sampling of the two components of the sex pheromone (total 2.2 mg at the source) of the almond moth (Ephestia cautella) female showed that the saturation period near the source in still air was 20–22 hr and that far from the source was 40–50 hr, reaching a level of less than 1 ng/ml air. The ratio between the components (Z,E)-9,12-tetradecadienyl acetate, designated D, and (Z)-9-tetradecenyl acetate designated M, in the air was close to the original ratio for both sampling sites, albeit somewhat richer in the more volatile (Z)-9-tetradecenyl acetate (source 77.023.0 DM, air 73.0– 74.327.0–25.7; source 80.119.9, air 77.622.4; source 25.174.9, air 23.976. 1 DM). The total amount of pheromone per milliliter of air was two to three times larger near the source than far from it at the early stages of the evaporation and saturation process. When the amount of pheromone applied to the source was tripled (7 mg), the amount far from the source was almost tripled, or the saturation time was cut by factor of two to three.     

注重形式美与提高鉴赏力——中国绘画鉴赏的理论与实践

长期以来,美术鉴赏教育走进了忽视形式美、专注所谓意义与价值的误区。培养"欣赏形式美的眼睛"是美术鉴赏教育的重点与难点。本文对"形式"、"形式美"、"艺术的形式本体"、"绘画艺术本体"概念进行了梳理和界定;紧密结合中国绘画鉴赏的教育实践,提出了提高中国绘画鉴赏力的审美理念、路径、方法。     

复杂电磁暂态下变压器差动保护异常动作行为分析及对策

随着电力系统结构与组成的复杂性增加,变压器差动保护发生原因不明的误、拒动作几率明显上升,给电网安全带来隐患,也影响工业生产的正常运行.分析变压器经历外部故障切除、有载合闸、非线性负荷投入、换流变合闸等复杂电磁暂态过程时基于二次谐波制动的差动保护误动的机理,指出TA局部暂态饱和、非线性特性元件的相互作用是造成上述保护误动的根本原因.并对换流变压器差动保护在故障情况下长延时动作的原因进行分析,基于相电压突变量和差流突变量的时差,提出一种能有效解决上述问题的变压器差动保护判据。在任何非故障的异常情况下,该时差总是存在,而内部故障时该时差很小,可以将变压器故障和其经历的异常运行状态相区分.通过大量的试验对该判据的可行性和有效性进行验证.     

改性聚氨酯固相微萃取吸附材料的合成及光谱分析

以羟基硅油、甲苯-2,4-二异氰酸酯（TDI）、聚己二酸乙二醇酯和1,6-己二醇为原料,以辛酸亚锡为催化剂,环己酮为溶剂,合成了有机硅-聚氨酯聚合物固相微萃取吸附材料。采用红外光谱法对聚合产物进行了结构表征。建立了分光光度法测定有机硅-聚氨酯共聚物中游离异氰酸酯基（NCO）含量的定量分析方法,吸光度与异氰酸基含量呈线性关系,相关系数为R2=0.9996。该方法相对标准偏差小于5%,回收率为99.4%～105%。考察了显色剂用量、体系的酸度、显色时间等因素对NCO测定结果的影响。     

基于新型免疫粒子群优化的热连轧负荷分配策略*

针对带钢热连轧精轧中的负荷分配问题,提出了一种新型的优化策略。首先提出了一种新型的免疫粒子群混合优化算法,通过克隆选择算子来调节群体的浓度,实现混合算法的个体高亲和力和群体的多样性; 然后通过提出的混合算法对负荷分配进行优化,得到优化的压下量数据,通过这些数据建立了计算负荷分配输出的人工神经网络。实验表明,提出的混合算法和负荷分配优化策略给出了很好的优化效果,能有效地指导实际生产应用。     

焙烧及改性对沸石吸附甲醛性能的影响

通过研究几种不同的焙烧方式对沸石吸附甲醛的影响,得出经过不同焙烧改性的沸石对甲醛均具有一定的吸附量,其中经过NaOH改性后再于400℃焙烧的沸石吸附量比较理想,达到0．1656g／g．     

股权结构、董事会特征与信息披露质量的关系研究

采用深交所对上市公司信息披露质量的评级作为信息披露质量代理变量,借助于多元排序选择模型检验了深交所上市公司股权结构、董事会特征对信息披露质量的影响.研究发现:信息披露的质量与控制变量--公司规模、财务业绩呈显著正相关,与公司财务杠杆之间的相关性不显著;股权集中度、第一大股东的性质、流通股比例、高管持股比例、董事会规模、董事会领导结构、独立董事比例等公司治理变量对信息披露质量的影响不显著,只有年度董事会会议次数与信息披露质量之间是显著负相关的.     

Fault-Diagnosis Method Based on Support Vector Machine and Artificial Immune for Batch Process

A new fault-diagnosis method to be used in batch processes based on multi-phase regression is presented to overcome the difficulty arising in the processes due to non-uniform sample data in each phase. Support vector machine is first used for phase identification, and for each phase, improved artificial immune network is developed to analyze and recognize fault patterns. A new cell elimination role is proposed to enhance the incremental clustering capability of the immune network. The proposed method has been applied to glutamic acid fermentation, comparison results have indicated that the proposed approach can better classify fault samples and yield higher diagnosis precision.     

基于移动机器人定位和导航的人工路标设计

在复杂环境下,如何快速、准确地识别路标是移动机器人定位和导航的关键问题.基于图像分割原理,利用投影和方向特征的处理方法,提出了一种新的人工路标方案.通过统计学的相关理论验证了该路标图案的可行性,实验结果也显示了该图案可以较好地解决移动机器人的路标识别问题.